Bioactivity | [IrCl(COE)2]2 (Chlorobis(cyclooctene)iridium(I)dimer) is a transition metal catalyst with remarkable catalytic activity. It is widely used in catalyzing a variety of organic reactions, especially in the synthesis of unsaturated compounds. In addition, [IrCl(COE)2]2 has shown potential anti-tumor properties in biochemical research. |
CAS | 12246-51-4 |
Formula | C32H56Cl2Ir2 |
Molar Mass | 896.13 |
Appearance | 固体 |
Transport | Room temperature in continental US; may vary elsewhere. |
Storage | 4°C, protect from light, stored under nitrogen *In solvent : -80°C, 6 months; -20°C, 1 month (protect from light, stored under nitrogen) |
Reference | [1]. Intermolecular, catalytic asymmetric hydroamination of bicyclic alkenes and dienes in high yield and enantioselectivity [2]. Transition-metal-catalyzed immobilization of organic functional groups onto solid supports through vinylsilane coupling reactions [3]. Iridium (I)-catalyzed hydrogen peroxide oxidation of hydroxamic acids and hetero DielsAlder reaction of the acyl nitroso intermediates with cyclopentadiene [4]. Alkylation of active methylene compounds with alcohols catalyzed by an iridium complex [5]. An efficient and recyclable catalytic system comprising nano-iridium (0) and a pyridinium salt of nido-carboranyldiphosphine for the synthesis of one-dimensional boronate esters via hydroboration reaction [6]. Allylic amination by a DNAdieneiridium (I) hybrid catalyst [7]. Versatile Pd (II)-Catalyzed C H Activation/Aryl Aryl Coupling of Benzoic and Phenyl Acetic Acids |